The Applications of Palladacycles as Transition-Metal Catalysts in Organic Synthesis

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	The Applications of Palladacycles as Transition-Metal Catalysts in Organic Synthesis
	Mo DL(莫冬亮)1; Zhang TK(张廷柯)1; Ge GC(葛广存)1; Huang XJ(黄小军)1; Ding CH(丁昌华)1; Dai LX(戴立信)1; Hou XL(侯雪龙)1
刊名	Synlett
	2014
卷号	25 期号:19 页码:2686-2702
其他题名	环钯作为过渡金属催化剂在有机合成中的应用
通讯作者	丁昌华 ; 侯雪龙
英文摘要	This account summarizes our recent work on palladacycles in organic synthesis and describes some unique catalytic properties of palladacycles as transition-metal catalysts for some useful transformations. Asymmetric induction has been realized by using chiral palladacycles as transition-metal catalysts. The influence of the C-Pd bond of palladacycles on their catalytic activity has been revealed. The reaction selectivity can be switched by appropriate choice of an sp(2)- or sp(3)-hybridized C,P-palladacycle catalyst. 1Introduction 2The Discovery of the Use of Palladacycles as Transition-Metal Catalysts and Their Applications in Asymmetric Catalysis 3Switch Between Addition and Ring Opening in the Reaction of Oxabicyclic Alkenes with Terminal Alkynes by Catalysis with sp(2)-C,P- or sp(3)-C,P-Palladacycles 4Synthesis of Polysubstituted Furans, Methylenecyclopropanes, and Polycyclic 5H-Benzo[b]azepines through Catalysis by Palladacycles 5Conclusions
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1055/s-0034-1379230
语种	英语
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/39126]
专题	上海有机化学研究所_金属有机化学国家重点实验室
作者单位	1.中科院上海有机化学研究所 2.广西师范大学
推荐引用方式 GB/T 7714	Mo DL,Zhang TK,Ge GC,et al. The Applications of Palladacycles as Transition-Metal Catalysts in Organic Synthesis[J]. Synlett,2014,25(19):2686-2702.
APA	莫冬亮.,张廷柯.,葛广存.,黄小军.,丁昌华.,...&侯雪龙.(2014).The Applications of Palladacycles as Transition-Metal Catalysts in Organic Synthesis.Synlett,25(19),2686-2702.
MLA	莫冬亮,et al."The Applications of Palladacycles as Transition-Metal Catalysts in Organic Synthesis".Synlett 25.19(2014):2686-2702.