Insertion of Nitriles into Zirconocene 1-aza-1,3-diene Complexes: Chemoselective Synthesis of N-H and N-Substituted Pyrroles | |
YU SHASHA; XIONG MEIJUN; XIE XIN; Liu YH(刘元红) | |
刊名 | Angew. Chem.-Int. Edit. |
2014 | |
卷号 | 53期号:43页码:11596-11599 |
其他题名 | Insertion of Nitriles into Zirconocene 1-aza-1,3-diene Complexes: Chemoselective Synthesis of N-H and N-Substituted Pyrroles |
英文摘要 | The direct insertion of nitriles into zirconocene-1-aza-1,3-diene complexes provides an efficient, chemoselective, and controllable synthesis of N-H and N-substituted pyrroles upon acidic aqueous work-up. The outcome of the reaction (that is, the formation of N-H or N-substituted pyrroles) results from the different cyclization patterns, which depend on the relative stability and reactivity of the enamine-imine tautomers formed by hydrolysis of the diazazirconacycles. |
学科主题 | 金属有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1002/anie.201407221 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.sioc.ac.cn/handle/331003/39118] |
专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
作者单位 | 中科院上海有机化学研究所 |
推荐引用方式 GB/T 7714 | YU SHASHA,XIONG MEIJUN,XIE XIN,et al. Insertion of Nitriles into Zirconocene 1-aza-1,3-diene Complexes: Chemoselective Synthesis of N-H and N-Substituted Pyrroles[J]. Angew. Chem.-Int. Edit.,2014,53(43):11596-11599. |
APA | YU SHASHA,XIONG MEIJUN,XIE XIN,&刘元红.(2014).Insertion of Nitriles into Zirconocene 1-aza-1,3-diene Complexes: Chemoselective Synthesis of N-H and N-Substituted Pyrroles.Angew. Chem.-Int. Edit.,53(43),11596-11599. |
MLA | YU SHASHA,et al."Insertion of Nitriles into Zirconocene 1-aza-1,3-diene Complexes: Chemoselective Synthesis of N-H and N-Substituted Pyrroles".Angew. Chem.-Int. Edit. 53.43(2014):11596-11599. |
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