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	Lewis Acid Triggered Reactivity of a Lewis Base Stabilized Scandium-Terminal Imido Complex: C-H Bond Activation, Cycloaddition, and Dehydrofluorination
	Chu JX(楚甲祥)1; Han XH(韩向豪)1; KEFALIDIS CHRISTOS E1; Zhou JL(周吉亮)1; MARON LAURENT1; Leng XB(冷雪冰)1; Chen YF(陈耀峰)1
刊名	J. Am. Chem. Soc.
	2014
卷号	136期号:31页码:10894-10897
其他题名	路易斯酸对一个路易斯碱稳定的钪末端氮宾反应性的激活: C-H键活化, 环加成和脱氟化氢
通讯作者	MARON LAURENT ; 陈耀峰
英文摘要	A stable scandium-terminal imido complex is activated by borane to form an unsaturated terminal imido complex by removing the coordinated Lewis base, 4-(dimethylamino)pyridine, from the metal center. The ensuing terminal imido intermediate can exist as a THF adduct and/or undergo cycloaddition reaction with an internal alkyne, C-H activation of a terminal alkene, and dehydrofluorination of fluoro-substituted benzenes or alkanes at room temperature. DFT investigations further highlight the ease of C-H activation for terminal alkene and fluoroarene. They also shed light on the mechanistic aspects of these two reactions.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/ja5061559
语种	英语
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/39083]
专题	上海有机化学研究所_金属有机化学国家重点实验室
作者单位	1.中科院上海有机化学研究所 2.法国图卢兹第三大学
推荐引用方式 GB/T 7714	Chu JX,Han XH,KEFALIDIS CHRISTOS E,et al. Lewis Acid Triggered Reactivity of a Lewis Base Stabilized Scandium-Terminal Imido Complex: C-H Bond Activation, Cycloaddition, and Dehydrofluorination[J]. J. Am. Chem. Soc.,2014,136(31):10894-10897.
APA	楚甲祥.,韩向豪.,KEFALIDIS CHRISTOS E.,周吉亮.,MARON LAURENT.,...&陈耀峰.(2014).Lewis Acid Triggered Reactivity of a Lewis Base Stabilized Scandium-Terminal Imido Complex: C-H Bond Activation, Cycloaddition, and Dehydrofluorination.J. Am. Chem. Soc.,136(31),10894-10897.
MLA	楚甲祥,et al."Lewis Acid Triggered Reactivity of a Lewis Base Stabilized Scandium-Terminal Imido Complex: C-H Bond Activation, Cycloaddition, and Dehydrofluorination".J. Am. Chem. Soc. 136.31(2014):10894-10897.

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