Gold-Catalyzed Cycloisomerization of Yne-Vinylidenecyclopropanes: A Three-Carbon Synthon for [3+2] Cycloadditions

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	Gold-Catalyzed Cycloisomerization of Yne-Vinylidenecyclopropanes: A Three-Carbon Synthon for [3+2] Cycloadditions
	Yuan W(袁渭); Tang XY(唐翔鹰); Wei Y(魏音); Shi M(施敏)
刊名	Chem.-Eur. J.
	2014
卷号	20 期号:11 页码:3198-3204
其他题名	金催化炔-亚乙烯基环丙烷的环异构化反应-3碳合成子的[3+2]环加成反应
通讯作者	魏音 ; 施敏
英文摘要	A novel type of yne-vinylidenecyclopropanes (VDCPs) has been synthesized and applied in gold-catalyzed cycloisomerization reactions. It was found that these compounds can undergo an intramolecular cycloisomerization and perform as a three-carbon synthon for [3+2] cycloaddition under gold catalysis to give fused [4.3.0] and [5.3.0] bicyclic derivatives and VDCP rearranged products in moderated to good yields under mild conditions. The substrate scope of these novel transformations has been explored and plausible reaction mechanisms have been presented on the basis of deuterium labeling experiments and DFT calculations.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1002/chem.201304579
语种	英语
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/39066]
专题	上海有机化学研究所_金属有机化学国家重点实验室
作者单位	中科院上海有机化学研究所
推荐引用方式 GB/T 7714	Yuan W,Tang XY,Wei Y,et al. Gold-Catalyzed Cycloisomerization of Yne-Vinylidenecyclopropanes: A Three-Carbon Synthon for [3+2] Cycloadditions[J]. Chem.-Eur. J.,2014,20(11):3198-3204.
APA	袁渭,唐翔鹰,魏音,&施敏.(2014).Gold-Catalyzed Cycloisomerization of Yne-Vinylidenecyclopropanes: A Three-Carbon Synthon for [3+2] Cycloadditions.Chem.-Eur. J.,20(11),3198-3204.
MLA	袁渭,et al."Gold-Catalyzed Cycloisomerization of Yne-Vinylidenecyclopropanes: A Three-Carbon Synthon for [3+2] Cycloadditions".Chem.-Eur. J. 20.11(2014):3198-3204.