A Cobalt-Catalyzed Alkene Hydroboration with Pinacolborane

CORC > 上海有机化学研究所 > 中国科学院上海有机化学研究所 > 金属有机化学国家重点实验室

	A Cobalt-Catalyzed Alkene Hydroboration with Pinacolborane
	Zhang L(张雷); Zuo ZQ(左自青); Leng XB(冷雪冰); Huang Z(黄正)
刊名	Angew. Chem.-Int. Edit.
	2014
卷号	53 期号:10 页码:2696-2700
其他题名	钴催化剂催化的利用频哪醇硼烷参与的烯烃硼氢化反应
通讯作者	黄正
英文摘要	An extremely efficient cobalt catalyst for the hydroboration of both vinylarenes and aliphatic -olefins with pinacolborane is described, providing the anti-Markovnikov products with excellent regio- and chemoselectivity, broad functional-group tolerance, and high turnover numbers (up to 19800). The alkene hydroboration route is further extended to a two-step, one-pot hydroboration and cross-coupling of alkylboronates with aryl chlorides.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1002/anie.201310096
语种	英语
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/39049]
专题	上海有机化学研究所_金属有机化学国家重点实验室
作者单位	中科院上海有机化学研究所
推荐引用方式 GB/T 7714	Zhang L,Zuo ZQ,Leng XB,et al. A Cobalt-Catalyzed Alkene Hydroboration with Pinacolborane[J]. Angew. Chem.-Int. Edit.,2014,53(10):2696-2700.
APA	张雷,左自青,冷雪冰,&黄正.(2014).A Cobalt-Catalyzed Alkene Hydroboration with Pinacolborane.Angew. Chem.-Int. Edit.,53(10),2696-2700.
MLA	张雷,et al."A Cobalt-Catalyzed Alkene Hydroboration with Pinacolborane".Angew. Chem.-Int. Edit. 53.10(2014):2696-2700.