Adsorption Performance of Methyl Violet via alpha-Fe2O3@Porous Hollow Carbonaceous Microspheres and Its Effective Regeneration through a Fenton-Like Reaction

	Adsorption Performance of Methyl Violet via alpha-Fe2O3@Porous Hollow Carbonaceous Microspheres and Its Effective Regeneration through a Fenton-Like Reaction
	Tong, Zhiqing 1; Zheng, Pei 1; Bai, Bo 1,2; Wang, Honglun 2; Suo, Yourui 2
刊名	catalysts
	2016-04-01
卷号	6 期号:4
关键词	alpha-Fe2O3@Porous hollow carbonaceous microspheres methyl violet equilibrium isotherm kinetics thermodynamics
英文摘要	alpha-fe2o3@porous hollow carbonaceous microspheres (alpha-fe2o3@phcms) were prepared through a combination of hydrothermal and calcination method. the novel alpha-fe2o3@phcms integrated the adsorptive and catalytic performances and served as an inexpensive adsorbent to rapidly remove cationic dye (methyl violet (mv)) from aqueous solution. equilibrium studies indicated that the dye molecules obeyed langmuir type of adsorption with the calculated maximum adsorption capacity of 539.8 mg.g(-1) at 313.15 k. kinetic data were better described by pseudo-second-order model and the thermodynamic studies illustrated that mv adsorption onto the composite was spontaneous, endothermic and occurred by physisorption. the fenton-like process was found to be effective for the regeneration of the spent alpha-fe2o3@phcms. the regeneration efficiency, as high as 88.0%, was still maintained after three consecutive adsorption-regeneration cycles. ftir and xrd characterizations of the composite before and after adsorption-regeneration treatment showed that the fenton-like process did not cause serious damage to the structure of composites.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, physical
研究领域[WOS]	chemistry
关键词[WOS]	aqueous-solution ; basic dye ; removal ; equilibrium ; adsorbent ; composite ; sorption ; water ; acid ; blue
收录类别	SCI
语种	英语
WOS记录号	WOS:000375210900010
内容类型	期刊论文
源URL	[http://ir.nwipb.ac.cn/handle/363003/5744]
专题	西北高原生物研究所_中国科学院西北高原生物研究所
作者单位	1.Changan Univ, Coll Environm Sci & Engn, Xian 710054, Peoples R China 2.Chinese Acad Sci, Northwest Inst Plateau Biol, Key Lab Tibetan Med Res, Xining 810001, Peoples R China
推荐引用方式 GB/T 7714	Tong, Zhiqing,Zheng, Pei,Bai, Bo,et al. Adsorption Performance of Methyl Violet via alpha-Fe2O3@Porous Hollow Carbonaceous Microspheres and Its Effective Regeneration through a Fenton-Like Reaction[J]. catalysts,2016,6(4).
APA	Tong, Zhiqing,Zheng, Pei,Bai, Bo,Wang, Honglun,&Suo, Yourui.(2016).Adsorption Performance of Methyl Violet via alpha-Fe2O3@Porous Hollow Carbonaceous Microspheres and Its Effective Regeneration through a Fenton-Like Reaction.catalysts,6(4).
MLA	Tong, Zhiqing,et al."Adsorption Performance of Methyl Violet via alpha-Fe2O3@Porous Hollow Carbonaceous Microspheres and Its Effective Regeneration through a Fenton-Like Reaction".catalysts 6.4(2016).