XAFS study of Fe/ZrO2 aerogel ultrafine particle catalysts | |
Hu TD(胡天斗)![]() ![]() ![]() ![]() ![]() | |
刊名 | ACTA CHIMICA SINICA
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1995 | |
卷号 | 53期号:11页码:1082-1087 |
通讯作者 | CHINESE ACAD SCI,INST COAL CHEM,TAIYUAN 030001,PEOPLES R CHINA |
英文摘要 | A series of Fe/ZrO2 catalysts with different particle size has been prepared by the supercritical fluid drying and conventional impregnation methods. The neighboring coordinative environment of iron in these catalysts was investigated by XAFS. The results show that as the particle size of Fe/ZrO2 catalysts is decreased, their structure is disorder gradually, the coordination number of the first Fe-O shell does not change and their Fe-O bond length has a litter shrink, The coordination number and bond length of the second Fe-O shell are decreased, and coordination number of higher coordination shell decreases very quickly. The correlation between the XAFS results and the activity and selectivity of these catalysts was obtained. |
学科主题 | Chemistry |
类目[WOS] | Chemistry, Multidisciplinary |
研究领域[WOS] | Chemistry |
原文出处 | SCI |
语种 | 英语 |
WOS记录号 | WOS:A1995TL44500008 |
内容类型 | 期刊论文 |
源URL | [http://ir.ihep.ac.cn/handle/311005/239015] ![]() |
专题 | 高能物理研究所_多学科研究中心 |
作者单位 | 中国科学院高能物理研究所 |
推荐引用方式 GB/T 7714 | Hu TD,Xiang HW,Xie YN,et al. XAFS study of Fe/ZrO2 aerogel ultrafine particle catalysts[J]. ACTA CHIMICA SINICA,1995,53(11):1082-1087. |
APA | 胡天斗.,相宏伟.,谢亚宁.,黄达贤.,陈贤能.,...&Peng, SY.(1995).XAFS study of Fe/ZrO2 aerogel ultrafine particle catalysts.ACTA CHIMICA SINICA,53(11),1082-1087. |
MLA | 胡天斗,et al."XAFS study of Fe/ZrO2 aerogel ultrafine particle catalysts".ACTA CHIMICA SINICA 53.11(1995):1082-1087. |
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