A Study on the Oxygen Vacancies in ZnPd/ZnO-Al and their Promoting Role in Glycerol Hydrogenolysis | |
Li,Xiaoru; Zhang,Chao; Cheng,Haiyang; Lin,Weiwei; Chang,Pingjing; Zhang,Bin; Wu,Qifan; Yu,Yancun; Zhao,Fengyu | |
刊名 | chemcatchem |
2015 | |
卷号 | 7期号:8页码:1322-1328 |
关键词 | GAS SHIFT REACTION SUPPORTED PALLADIUM CATALYSTS DOPED ZNO FILMS CO OXIDATION ZINC-OXIDE REFORMING-HYDROGENOLYSIS METHANOL SYNTHESIS PD/ZNO CATALYSTS PROPYLENE-GLYCOL AU NANOPARTICLES |
通讯作者 | zhang,c |
英文摘要 | the relationship between catalyst structure and catalytic activity is an important and challenging topic for researchers in the field of catalysis. in this work, the effect of oxygen vacancies on the activity of znpd/zno-al catalysts was studied in an important reaction-glycerol hydrogenolysis. interestingly, the catalytic activity improved significantly with the addition of a small amount of al, and high selectivity to 1,2-propanediol (>90%) was achieved in glycerol hydrogenolysis over znpd/zno-al catalysts. importantly, the formation of oxygen vacancies benefits from the substitution of al atoms, and the al content in the zno lattice is related to the oxygen vacancies density and catalytic activity. moreover, the important role played by oxygen vacancies in glycerol hydrogenolysis has been discussed in detail. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2016-05-31 |
内容类型 | 期刊论文 |
源URL | [http://ir.ciac.jl.cn/handle/322003/65117] |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Li,Xiaoru,Zhang,Chao,Cheng,Haiyang,et al. A Study on the Oxygen Vacancies in ZnPd/ZnO-Al and their Promoting Role in Glycerol Hydrogenolysis[J]. chemcatchem,2015,7(8):1322-1328. |
APA | Li,Xiaoru.,Zhang,Chao.,Cheng,Haiyang.,Lin,Weiwei.,Chang,Pingjing.,...&Zhao,Fengyu.(2015).A Study on the Oxygen Vacancies in ZnPd/ZnO-Al and their Promoting Role in Glycerol Hydrogenolysis.chemcatchem,7(8),1322-1328. |
MLA | Li,Xiaoru,et al."A Study on the Oxygen Vacancies in ZnPd/ZnO-Al and their Promoting Role in Glycerol Hydrogenolysis".chemcatchem 7.8(2015):1322-1328. |
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