A Study on the Oxygen Vacancies in ZnPd/ZnO-Al and their Promoting Role in Glycerol Hydrogenolysis
Li,Xiaoru; Zhang,Chao; Cheng,Haiyang; Lin,Weiwei; Chang,Pingjing; Zhang,Bin; Wu,Qifan; Yu,Yancun; Zhao,Fengyu
刊名chemcatchem
2015
卷号7期号:8页码:1322-1328
关键词GAS SHIFT REACTION SUPPORTED PALLADIUM CATALYSTS DOPED ZNO FILMS CO OXIDATION ZINC-OXIDE REFORMING-HYDROGENOLYSIS METHANOL SYNTHESIS PD/ZNO CATALYSTS PROPYLENE-GLYCOL AU NANOPARTICLES
通讯作者zhang,c
英文摘要the relationship between catalyst structure and catalytic activity is an important and challenging topic for researchers in the field of catalysis. in this work, the effect of oxygen vacancies on the activity of znpd/zno-al catalysts was studied in an important reaction-glycerol hydrogenolysis. interestingly, the catalytic activity improved significantly with the addition of a small amount of al, and high selectivity to 1,2-propanediol (>90%) was achieved in glycerol hydrogenolysis over znpd/zno-al catalysts. importantly, the formation of oxygen vacancies benefits from the substitution of al atoms, and the al content in the zno lattice is related to the oxygen vacancies density and catalytic activity. moreover, the important role played by oxygen vacancies in glycerol hydrogenolysis has been discussed in detail.
收录类别SCI
语种英语
公开日期2016-05-31
内容类型期刊论文
源URL[http://ir.ciac.jl.cn/handle/322003/65117]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Li,Xiaoru,Zhang,Chao,Cheng,Haiyang,et al. A Study on the Oxygen Vacancies in ZnPd/ZnO-Al and their Promoting Role in Glycerol Hydrogenolysis[J]. chemcatchem,2015,7(8):1322-1328.
APA Li,Xiaoru.,Zhang,Chao.,Cheng,Haiyang.,Lin,Weiwei.,Chang,Pingjing.,...&Zhao,Fengyu.(2015).A Study on the Oxygen Vacancies in ZnPd/ZnO-Al and their Promoting Role in Glycerol Hydrogenolysis.chemcatchem,7(8),1322-1328.
MLA Li,Xiaoru,et al."A Study on the Oxygen Vacancies in ZnPd/ZnO-Al and their Promoting Role in Glycerol Hydrogenolysis".chemcatchem 7.8(2015):1322-1328.
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