Asymmetric hydrogenation of alpha-keto phosphonates with chiral phosphine-phosphoramidite ligands

	Asymmetric hydrogenation of alpha-keto phosphonates with chiral phosphine-phosphoramidite ligands
	Li, Qing 1,2; Hou, Chuan-Jin 1,2; Liu, Yan-Jun 1; Yang, Rui-Feng 1; Hu, Xiang-Ping 2
刊名	tetrahedron-asymmetry
	2015-07-15
卷号	26 期号:12-13 页码:617-622
英文摘要	rh-catalyzed asymmetric hydrogenation of challenging alpha-keto phosphonates has been developed. with a new chiral phosphine-phosphoramidite ligand, a wide range of alpha-keto phosphonates were hydrogenated to afford the corresponding (r)-alpha-hydroxy phosphonates with moderate to good enantioselectivities (up to 87% ee). (c) 2015 elsevier ltd. all rights reserved.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, inorganic & nuclear ; chemistry, organic ; chemistry, physical
研究领域[WOS]	chemistry
关键词[WOS]	catalyzed enantioselective hydrogenation ; hydroxy phosphonates ; beta-ketoesters ; al(salalen) complex ; diphosphine ligands ; kinetic resolution ; n-arylimines ; hydrophosphonylation ; aldehydes ; hydroxyphosphonates
收录类别	SCI
语种	英语
WOS记录号	WOS:000356557200004
公开日期	2016-05-09
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/146342]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Dalian Polytech Univ, Sch Light Ind & Chem Engn, Dalian 116034, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Li, Qing,Hou, Chuan-Jin,Liu, Yan-Jun,et al. Asymmetric hydrogenation of alpha-keto phosphonates with chiral phosphine-phosphoramidite ligands[J]. tetrahedron-asymmetry,2015,26(12-13):617-622.
APA	Li, Qing,Hou, Chuan-Jin,Liu, Yan-Jun,Yang, Rui-Feng,&Hu, Xiang-Ping.(2015).Asymmetric hydrogenation of alpha-keto phosphonates with chiral phosphine-phosphoramidite ligands.tetrahedron-asymmetry,26(12-13),617-622.
MLA	Li, Qing,et al."Asymmetric hydrogenation of alpha-keto phosphonates with chiral phosphine-phosphoramidite ligands".tetrahedron-asymmetry 26.12-13(2015):617-622.