Magnetic Field Enhanced Photoelectron Ionization Source Portable TOF-MS and Its Application in Analysis of Volatile Reduced Sulfur Compounds

	Magnetic Field Enhanced Photoelectron Ionization Source Portable TOF-MS and Its Application in Analysis of Volatile Reduced Sulfur Compounds
	Li Jin-Xu 1; Hou Ke-Yong 2; Zhao Wu-Duo 2; Chen Wen-Dong 2,3; Jiang Ji-Chun 2,3; Liu Wei 2,3; Li Qing-Yun 1; Tian Di 1; Li Hai-Yang 1
刊名	chinese journal of analytical chemistry
	2015-03-01
卷号	43 期号:3 页码:444-450
关键词	Volatile reduced sulfur compounds Magnetic field enhanced photoelectron ionization Portable time-of-flight mass spectrometer Online monitoring
英文摘要	reduced sulfur compounds (rscs) are one of the main pollutant species in the atmosphere, so it is of great significance to develop a rapid and on. line approaches for their detection. in this study, a portable time. of. flight mass spectrometer (tof-ms) with magnetic field enhanced photoelectron ionization source was designed to detect rscs. the photoelectron ionization source was induced from vacuum ultraviolet photons which generated from vacuum ultraviolet (vuv) lamp with energy of 10. 6 ev. the energy of photoelectrons was controlled by adjusting the extraction voltage to produce the photoelectron ionization, and an annular magnet was used in the ionization region to improve the ionization efficiency of photoelectrons. from the simulation result by simion software, it was found that the introduction of magnet field made the motion trajectroies of electrons in the helical motion increase and the convergence of electron at the ionization source was achieved. experimental results showed that after introducing the magnet filed, the sensitivity of h2s, so2 and cs2 was improved by a factor of 5. 3, 9. 4 and 6. 9, respectively. with a detection time of 50 s, the limits of detection for h2s, so2 and cs2 were 0. 14, 0. 52 and 0. 31 mg/m(3)(s/n = 3), respectively. it could be concluded that the portable tof. ms with magnetic field enhanced photoelectron ionization source has great potential to be applied for on. line monitoring of volatile sulfides at the emission source.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, analytical
研究领域[WOS]	chemistry
关键词[WOS]	single-photon ionization ; electron-impact ionization ; flight mass-spectrometry ; vacuum-ultraviolet lamp ; system ; dioxide
收录类别	SCI
语种	英语
WOS记录号	WOS:000354901600017
公开日期	2016-05-09
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/146251]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Jilin Univ, Coll Instrumentat & Elect Engn, Changchun 130023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Li Jin-Xu,Hou Ke-Yong,Zhao Wu-Duo,et al. Magnetic Field Enhanced Photoelectron Ionization Source Portable TOF-MS and Its Application in Analysis of Volatile Reduced Sulfur Compounds[J]. chinese journal of analytical chemistry,2015,43(3):444-450.
APA	Li Jin-Xu.,Hou Ke-Yong.,Zhao Wu-Duo.,Chen Wen-Dong.,Jiang Ji-Chun.,...&Li Hai-Yang.(2015).Magnetic Field Enhanced Photoelectron Ionization Source Portable TOF-MS and Its Application in Analysis of Volatile Reduced Sulfur Compounds.chinese journal of analytical chemistry,43(3),444-450.
MLA	Li Jin-Xu,et al."Magnetic Field Enhanced Photoelectron Ionization Source Portable TOF-MS and Its Application in Analysis of Volatile Reduced Sulfur Compounds".chinese journal of analytical chemistry 43.3(2015):444-450.