Promoted role of Cu(NO3)(2) on aerobic oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran over VOSO4

	Promoted role of Cu(NO3)(2) on aerobic oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran over VOSO4
	Jia, Xiuquan 1,2; Ma, Jiping 1; Wang, Min 1; Du, Zhongtian 1; Lu, Fang 1; Wang, Feng 1; Xu, Jie 1
刊名	applied catalysis a-general
	2014-07-22
卷号	482 页码:231-236
关键词	Catalysis Copper nitrate 2 Oxidation Sustainable chemistry 5-Diformylfuran
英文摘要	the promoted effect of cu(no3)(2) on aerobic oxidation of 5-hydroxymethylfurfural (hmf) to 2,5-diformylfuran (dff) catalyzed by voso4 in acetonitrile was intensively investigated. it was revealed that cu(no3)(2) facilitated the activation of voso4 to generate active v5+ species via the generation of no gas. the high off selectivity is ascribed to cu2+ cation which can effectively prohibit oxidative c-c bond cleavage reaction of hmf and prevent radical reaction of off to humins. in addition, the polarity of solvent plays a great role on high selectivity of off. (c) 2014 elsevier b.v. all rights reserved.
WOS标题词	science & technology ; physical sciences ; life sciences & biomedicine
类目[WOS]	chemistry, physical ; environmental sciences
研究领域[WOS]	chemistry ; environmental sciences & ecology
关键词[WOS]	selective oxidation ; one-pot ; lignocellulosic biomass ; catalytic conversion ; renewable resources ; supported ruthenium ; molecular-oxygen ; vanadyl sulfate ; mild conditions ; alkyl radicals
收录类别	SCI
语种	英语
WOS记录号	WOS:000340306500028
公开日期	2016-05-09
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/145401]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Jia, Xiuquan,Ma, Jiping,Wang, Min,et al. Promoted role of Cu(NO3)(2) on aerobic oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran over VOSO4[J]. applied catalysis a-general,2014,482:231-236.
APA	Jia, Xiuquan.,Ma, Jiping.,Wang, Min.,Du, Zhongtian.,Lu, Fang.,...&Xu, Jie.(2014).Promoted role of Cu(NO3)(2) on aerobic oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran over VOSO4.applied catalysis a-general,482,231-236.
MLA	Jia, Xiuquan,et al."Promoted role of Cu(NO3)(2) on aerobic oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran over VOSO4".applied catalysis a-general 482(2014):231-236.