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Efficient perovskite/fullerene planar heterojunction solar cells with enhanced charge extraction and suppressed charge recombination
Li, Cong1; Wang, Fuzhi1; Xu, Jia1; Yao, Jianxi1; Zhang, Bing1; Zhang, Chunfeng2,3; Xiao, Min2,3; Dai, Songyuan1; Li, Yongfang4; Tan, Zhan'ao1
刊名NANOSCALE
2015
卷号7期号:21页码:9771-9778
英文摘要Alcohol soluble titanium chelate TIPD (titanium (diisopropoxide) bis(2,4-pentanedionate)) was used as an electron transporting layer to form an ohmic contact with the negative electrode, aiming to enhance the charge extraction and suppress the charge recombination for high performance CH3NH3PbI3/PCBM-based PHJ perovskite solar cells. The TIPD layer shows excellent suitability to CH3NH3PbI3 perovskite synthesized by different methods. For one-step synthesized CH3NH3PbI3, the power conversion efficiency (PCE) of the device with the TIPD buffer reaches 8.75%, with a nearly 33% increase in comparison with the device without the buffer layer (6.58%). For two-step synthesized CH3NH3PbI3, an open-circuit voltage (V-oc) of 0.89 V, a short-circuit current density (J(sc)) of 22.57 mA cm(-2), and a fill factor (FF) of 64.5%, corresponding to a PCE of 12.95% for the device with a TIPD buffer layer were achieved, which is among the best performances reported in the literature for CH3NH3PbI3/PCBM-based PHJ perovskite solar cells.
收录类别SCI
语种英语
公开日期2016-05-09
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/28142]  
专题化学研究所_有机固体实验室
作者单位1.North China Elect Power Univ, Beijing Key Lab Novel Thin Film Solar Cells, Beijing 102206, Peoples R China
2.Nanjing Univ, Natl Lab Solid State Microstruct, Sch Phys, Nanjing 210093, Jiangsu, Peoples R China
3.Nanjing Univ, Sch Engn & Appl Sci, Nanjing 210093, Jiangsu, Peoples R China
4.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Li, Cong,Wang, Fuzhi,Xu, Jia,et al. Efficient perovskite/fullerene planar heterojunction solar cells with enhanced charge extraction and suppressed charge recombination[J]. NANOSCALE,2015,7(21):9771-9778.
APA Li, Cong.,Wang, Fuzhi.,Xu, Jia.,Yao, Jianxi.,Zhang, Bing.,...&Tan, Zhan'ao.(2015).Efficient perovskite/fullerene planar heterojunction solar cells with enhanced charge extraction and suppressed charge recombination.NANOSCALE,7(21),9771-9778.
MLA Li, Cong,et al."Efficient perovskite/fullerene planar heterojunction solar cells with enhanced charge extraction and suppressed charge recombination".NANOSCALE 7.21(2015):9771-9778.
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