Photoelectron Imaging Spectroscopy of ZrO- Diatomic Anion

	Photoelectron Imaging Spectroscopy of ZrO- Diatomic Anion
	Liu, Qing-yu 1; Hu, Lian-rui 2; Chen, Hui 2; He, Sheng-gui 1
刊名	CHINESE JOURNAL OF CHEMICAL PHYSICS
	2015-08-01
卷号	28 期号:4 页码:452-458
关键词	Diatomic molecules Electronic structure Spin-orbit splitting Photoelectron imaging spectroscopy ab initio calculations
英文摘要	The diatomic ZrO- anion has been prepared by laser ablation and studied by photoelectron imaging spectroscopy combined with quantum chemistry calculations. The observed photoelectron spectra can be well assigned on the basis of reported optical spectroscopy and high-level ab initio calculations. The ground state of ZrO- is a 2,6, state with spin-orbit splitting of 578 +/- 12 cm(-1). The electron affinity of ZrO is 1.249 +/- 0.005 eV. For the first time, the c(3)Sigma(-) state of ZrO has been experimentally observed at 13316 +/- 24 cm(-1) with respect to the X-1 Sigma(+) ground state. A comparison between ZrO and the isoelectronic molecule NbN has been made.
收录类别	SCI
语种	英语
公开日期	2016-05-09
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/28377]
专题	化学研究所_光化学实验室
作者单位	1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Key Lab Photochem, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Liu, Qing-yu,Hu, Lian-rui,Chen, Hui,et al. Photoelectron Imaging Spectroscopy of ZrO- Diatomic Anion[J]. CHINESE JOURNAL OF CHEMICAL PHYSICS,2015,28(4):452-458.
APA	Liu, Qing-yu,Hu, Lian-rui,Chen, Hui,&He, Sheng-gui.(2015).Photoelectron Imaging Spectroscopy of ZrO- Diatomic Anion.CHINESE JOURNAL OF CHEMICAL PHYSICS,28(4),452-458.
MLA	Liu, Qing-yu,et al."Photoelectron Imaging Spectroscopy of ZrO- Diatomic Anion".CHINESE JOURNAL OF CHEMICAL PHYSICS 28.4(2015):452-458.