Photoelectric behavior of nanocrystalline TiO2 electrode with a novel terpyridyl ruthenium complex
Wang, ZS; Huang, CH; Huang, YY; Zhang, BW; Xie, PH; Hou, YJ; Ibrahim, K; Qian, HJ; Liu, FQ; Kui RX(奎热西)
刊名SOLAR ENERGY MATERIALS AND SOLAR CELLS
2002
卷号71期号:2页码:#REF!
关键词Gratzel cell black dye TiO2 nanocrystalline TiO2 dye sensitized solar cell terpyridyl ruthenium dyes photoelectrochemical solar cells
通讯作者Huang, CH (reprint author), Peking Univ, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China.
英文摘要The photoelectric behavior of a black dye, tris (isothiocyanato)-[N-(2,2':6', 2"-terpyridine-4-(4-carbuxylic acid) phenyl)] ruthenium (II) complex, was examined under different conditions. The dye was adsorbed on nanocrystalline TiO2 surface strongly and generated incident monochromatic photon-to-current conversion efficiency (IPCE) of about 90% at maximum absorption wavelength and greater than 20% in the near-IR region. A sandwich-type solar cell fabricated by this dye-sensitized nanocrystalline TiO2 film generated 6.1 mA cm(-2) of short-circuit photocurrent, 0.58 V of open-circuit photovoltage and 2.9% of overall yield under irradiation of white light (78,0 mW cm(-2)) from a Xe lamp. Since the title dye shows better photoresponse than the N3 dye in the near-IR region, it would be a promising panchromatic sensitizer after optimization. (C) 2002 Elsevier Science B.V. All rights reserved.
学科主题Energy & Fuels; Materials Science; Physics
类目[WOS]Energy & Fuels ; Materials Science, Multidisciplinary ; Physics, Applied
收录类别SCI
WOS记录号WOS:000173184700011
公开日期2016-05-03
内容类型期刊论文
源URL[http://ir.ihep.ac.cn/handle/311005/227258]  
专题高能物理研究所_多学科研究中心
推荐引用方式
GB/T 7714
Wang, ZS,Huang, CH,Huang, YY,et al. Photoelectric behavior of nanocrystalline TiO2 electrode with a novel terpyridyl ruthenium complex[J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS,2002,71(2):#REF!.
APA Wang, ZS.,Huang, CH.,Huang, YY.,Zhang, BW.,Xie, PH.,...&刘凤琴.(2002).Photoelectric behavior of nanocrystalline TiO2 electrode with a novel terpyridyl ruthenium complex.SOLAR ENERGY MATERIALS AND SOLAR CELLS,71(2),#REF!.
MLA Wang, ZS,et al."Photoelectric behavior of nanocrystalline TiO2 electrode with a novel terpyridyl ruthenium complex".SOLAR ENERGY MATERIALS AND SOLAR CELLS 71.2(2002):#REF!.
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