Synthesis of novel hyper-cross-linked polymers as adsorbent for removing organic pollutants from humid streams
Wang, Wan-Qiu; Wang, Junhui; Chen, Jian-Gang; Fan, Xiu-Shan; Liu, Zhao-Tie; Liu, Zhong-Wen; Jiang, Jinqiang; Hao, Zhengping
刊名CHEMICAL ENGINEERING JOURNAL
2015-12-01
卷号281页码:34-41
关键词Hydrophobic HCPs VOCs adsorption Dynamic adsorption/desorption Static adsorption/desorption
英文摘要A new kind of hydrophobic hyper-cross-linked polymers (HCPs) with high surface area, large pore volume, and controllable average pore size was prepared. The synthesized HCP-0.5 sample, having the biggest BET specific surface area (1394 m(2)/g), pore volume (1.55 m(3)/g) and micro-mesopore structure (average pore diameter of 4.4 nm), was used as a novel adsorbent for removing benzene. The results of the static adsorption/desorption experiment at 298,308 and 318 K showed that HCP-0.5 has a very large adsorption capability of 19.16 mmol g(-1) at 298 K for benzene. Dynamic adsorption experiments of benzene on HCP-0.5 under dry and humid condition (RH = 80%) revealed that the existence of water vapor had little effect on dynamic adsorption capacity of benzene on HCP-0.5 and almost did not change the breakthrough time. Therefore, these synthesized polymers can be used as efficient and competitive adsorbents for removing VOCs, especially under humid conditions. (C) 2015 Elsevier B.V. All rights reserved.
研究领域[WOS]Engineering, Environmental ; Engineering, Chemical
WOS记录号WOS:000362308200004
公开日期2016-03-15
内容类型期刊论文
源URL[http://ir.rcees.ac.cn/handle/311016/32860]  
专题生态环境研究中心_环境水质学国家重点实验室
推荐引用方式
GB/T 7714
Wang, Wan-Qiu,Wang, Junhui,Chen, Jian-Gang,et al. Synthesis of novel hyper-cross-linked polymers as adsorbent for removing organic pollutants from humid streams[J]. CHEMICAL ENGINEERING JOURNAL,2015,281:34-41.
APA Wang, Wan-Qiu.,Wang, Junhui.,Chen, Jian-Gang.,Fan, Xiu-Shan.,Liu, Zhao-Tie.,...&Hao, Zhengping.(2015).Synthesis of novel hyper-cross-linked polymers as adsorbent for removing organic pollutants from humid streams.CHEMICAL ENGINEERING JOURNAL,281,34-41.
MLA Wang, Wan-Qiu,et al."Synthesis of novel hyper-cross-linked polymers as adsorbent for removing organic pollutants from humid streams".CHEMICAL ENGINEERING JOURNAL 281(2015):34-41.
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