Direct Conversion of Sugars and Ethyl Levulinate into gamma-Valerolactone with Superparamagnetic Acid-Base Bifunctional ZrFeOx Nanocatalysts

CORC > 西双版纳热带植物园 > 中国科学院西双版纳热带植物园 > 生物能源研究组

	Direct Conversion of Sugars and Ethyl Levulinate into gamma-Valerolactone with Superparamagnetic Acid-Base Bifunctional ZrFeOx Nanocatalysts
	Li, H (Li, Hu) ; Fang, Z (Fang, Zhen) ; Yang, S (Yang, Song)
刊名	ACS SUSTAINABLE CHEMISTRY & ENGINEERING
	2016
卷号	4 期号:1 页码:236-246
关键词	Nanocatalyst Biomass Biofuels Heterogeneous catalysis Acid-base sites Magnetism
中文摘要	Acid-base bifunctional superparamagnetic FeZrOx nanoparticles were synthesized via a two-step process of solvothermal treatment and hydrolysis-condensation, and were further employed to catalyze the conversion of ethyl levulinate (EL) to gamma-valerolactone (GVL) using ethanol as both H-donor and solvent. ZrFeO(1:3)-300 nanoparticles (12.7 nm) with Fe3O4 core covered by ZrO2 layer (0.65 nm thickness) having well-distributed acid-base sites (0.39 vs 0.28 mmol/g), moderate surface area (181 m(2)/g), pore size (9.8 nm), and strong magnetism (35.4 Am-2 kg(-1)) exhibited superior catalytic performance, giving a high GVL yield of 87.2% at 230 degrees C in 3 h. The combination of the nanoparticles with solid acid HY2.6 promoted the direct transformation of sugars to produce GVL in moderate yield (around 45%). Moreover, the nanocatalyst was easily recovered by a magnet for six cycles with an average GVL yield of 83.9% from EL.
公开日期	2016-02-01
内容类型	期刊论文
源URL	[http://ir.xtbg.org.cn/handle/353005/9653]
专题	西双版纳热带植物园_生物能源研究组
推荐引用方式 GB/T 7714	Li, H ,Fang, Z ,Yang, S . Direct Conversion of Sugars and Ethyl Levulinate into gamma-Valerolactone with Superparamagnetic Acid-Base Bifunctional ZrFeOx Nanocatalysts[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2016,4(1):236-246.
APA	Li, H ,Fang, Z ,&Yang, S .(2016).Direct Conversion of Sugars and Ethyl Levulinate into gamma-Valerolactone with Superparamagnetic Acid-Base Bifunctional ZrFeOx Nanocatalysts.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,4(1),236-246.
MLA	Li, H ,et al."Direct Conversion of Sugars and Ethyl Levulinate into gamma-Valerolactone with Superparamagnetic Acid-Base Bifunctional ZrFeOx Nanocatalysts".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 4.1(2016):236-246.