Palladium-Catalyzed Intermolecular Aryldifluoroalkylation of Alkynes

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	Palladium-Catalyzed Intermolecular Aryldifluoroalkylation of Alkynes
	He, Yu-Tao 1; Wang, Qiang 1; Li, Lian-Hua 1; Liu XY(刘雪原)1; Xu PF(许鹏飞)1; Liang YM(梁永民)1,2
刊名	Organic Letters
	2015
卷号	17 期号:21 页码:5188-5191
ISSN号	1523-7060
通讯作者	梁永民
英文摘要	A palladium-catalyzed aryldifluoroalkylation of alkynes with ethyl difluoroiodoacetate and arylboronic acids as reaction partners is described. The alkyne difunctionalization process provides various aryldifluoroalkylated products in one pot under mild reaction conditions. A wide range of alkynes and diverse arylboronic acids are compatible with these reaction conditions. High reaction efficiency and broad substrate scope are the notable features of this transformation. Preliminary mechanistic investigations indicate that a difluoroalkyl radical addition pathway is involved in this transformation.
学科主题	材料科学与物理化学
收录类别	SCI
资助信息	the National Natural Science Foundation (NSF 21272101;21472074;21472073);the Fundamental Research Funds for Central Universities (lzujbky-2014-243);the "111" Project (J1103307);Program for Changjiang Scholars and Innovative Research Team in University (IRT1138)
语种	英语
WOS记录号	WOS:000364434900011
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/19079]
专题	兰州化学物理研究所_固体润滑国家重点实验室
作者单位	1.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
推荐引用方式 GB/T 7714	He, Yu-Tao,Wang, Qiang,Li, Lian-Hua,et al. Palladium-Catalyzed Intermolecular Aryldifluoroalkylation of Alkynes[J]. Organic Letters,2015,17(21):5188-5191.
APA	He, Yu-Tao,Wang, Qiang,Li, Lian-Hua,Liu XY,Xu PF,&Liang YM.(2015).Palladium-Catalyzed Intermolecular Aryldifluoroalkylation of Alkynes.Organic Letters,17(21),5188-5191.
MLA	He, Yu-Tao,et al."Palladium-Catalyzed Intermolecular Aryldifluoroalkylation of Alkynes".Organic Letters 17.21(2015):5188-5191.