Diels-Alder/Oxidative Aromatization Approach towards the All- Carbon DEF Tricyclic Skeleton of Daphenylline

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	Diels-Alder/Oxidative Aromatization Approach towards the All- Carbon DEF Tricyclic Skeleton of Daphenylline
	Li HL(李辉林)1; Qiu, Yangcheng 1; Zhao CG(赵常贵)1; Yuan, Ziyun 1; Xie XG(谢新刚)1; She XG(厍学功)1,2
刊名	Chemistry - An Asian Journal
	2014
卷号	9 期号:5 页码:1274-1277
关键词	alkaloids aromatization daphenylline Diels-Alder natural products
ISSN号	1861-4728
通讯作者	厍学功
英文摘要	Daphenylline is a recently isolated Daphniphyllum alkaloid with an unprecedented novel hexacyclic scaffold. In this study, the synthesis of the fused all-carbon DEF tricyclic skeleton of daphenylline has been accomplished. Key steps of the reported sequence involve Evans asymmetric allylation, aldol condensation, Diels-Alder reaction, and oxidative aromatization reactions. The developed strategy might lead to the total synthesis of daphenylline.
学科主题	物理化学与绿色催化
收录类别	SCI
资助信息	the NSFC (21125207;21372103;21102062);the MOST (2010CB833200);FRFCU (lzujbky-2013-49;lzujbky-2013-ct02)
语种	英语
WOS记录号	WOS:000334779000010
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/19263]
专题	兰州化学物理研究所_OSSO国家重点实验室
作者单位	1.Lanzhou Univ, State Key Lab Appl Organ Chem, Dept Chem, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China
推荐引用方式 GB/T 7714	Li HL,Qiu, Yangcheng,Zhao CG,et al. Diels-Alder/Oxidative Aromatization Approach towards the All- Carbon DEF Tricyclic Skeleton of Daphenylline[J]. Chemistry - An Asian Journal,2014,9(5):1274-1277.
APA	Li HL,Qiu, Yangcheng,Zhao CG,Yuan, Ziyun,Xie XG,&She XG.(2014).Diels-Alder/Oxidative Aromatization Approach towards the All- Carbon DEF Tricyclic Skeleton of Daphenylline.Chemistry - An Asian Journal,9(5),1274-1277.
MLA	Li HL,et al."Diels-Alder/Oxidative Aromatization Approach towards the All- Carbon DEF Tricyclic Skeleton of Daphenylline".Chemistry - An Asian Journal 9.5(2014):1274-1277.