Pd(PrSO3)(2)@SBA-15 and Pd-NPs(PrSO3)@SBA-15 hybrid materials: A highly active, reusable, and selective interface catalyst for C-X activations in air and water

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	Pd(PrSO3)(2)@SBA-15 and Pd-NPs(PrSO3)@SBA-15 hybrid materials: A highly active, reusable, and selective interface catalyst for C-X activations in air and water
	Rostamnia, Sadegh 1; Rahmani, Turaj 1; Xin, Hongchuan 2
刊名	JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
	2015-12-25
卷号	32 页码:218-224
关键词	Pd(PrSO3)(2)@SBA-15 Pd-NPs(PrSO3)@SBA-15 Interface catalyst Suzuld C-X activations
英文摘要	A series of ordered mesoporous organic-inorganic hybrid material are designed by using the SO3H-functionalized SBA-15 [(PdX2@SBA-15/SO3H or Pd(PrSO3)(2)@SBA-15) and (Pd-NPs@SBA-15/SO3H or Pd-NPs(PrSO3)@SBA-15)] as solid supports for palladium ions. Among them, the encapsulated Pd(MeCN)(2)Cl-2 into the SBA-15/SO3H and Pd-NPs@SBA-15/SO3H exhibit higher activity and selectivity toward Suzuki cross-coupling reaction in aerobic condition and water/DMF solvent. These heterogeneous palladium precatalysts could be separated from the reaction mixture and reused at least 11 times. (C) 2015 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
WOS标题词	Science & Technology ; Physical Sciences ; Technology
类目[WOS]	Chemistry, Multidisciplinary ; Engineering, Chemical
研究领域[WOS]	Chemistry ; Engineering
关键词[WOS]	MIYAURA COUPLING REACTIONS ; MAGNETIC NANOPARTICLES ; NANOPOROUS SILICA ; MESOPOROUS SILICA ; GREEN ; PALLADIUM ; HECK ; EFFICIENT ; HYDROGENATION ; NANOCOMPOSITE
收录类别	SCI
语种	英语
WOS记录号	WOS:000365368200028
公开日期	2016-02-26
内容类型	期刊论文
源URL	[http://ir.qibebt.ac.cn/handle/337004/6798]
专题	青岛生物能源与过程研究所_科技发展部
作者单位	1.Univ Maragheh, Fac Sci, Dept Chem, Organ & Nano Grp, Maragheh 5518183111, Iran 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biofuels, Qingdao 266101, Peoples R China
推荐引用方式 GB/T 7714	Rostamnia, Sadegh,Rahmani, Turaj,Xin, Hongchuan. Pd(PrSO3)(2)@SBA-15 and Pd-NPs(PrSO3)@SBA-15 hybrid materials: A highly active, reusable, and selective interface catalyst for C-X activations in air and water[J]. JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY,2015,32:218-224.
APA	Rostamnia, Sadegh,Rahmani, Turaj,&Xin, Hongchuan.(2015).Pd(PrSO3)(2)@SBA-15 and Pd-NPs(PrSO3)@SBA-15 hybrid materials: A highly active, reusable, and selective interface catalyst for C-X activations in air and water.JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY,32,218-224.
MLA	Rostamnia, Sadegh,et al."Pd(PrSO3)(2)@SBA-15 and Pd-NPs(PrSO3)@SBA-15 hybrid materials: A highly active, reusable, and selective interface catalyst for C-X activations in air and water".JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY 32(2015):218-224.