Rhodium-Catalyzed Asymmetric Arylation of beta,gamma-Unsaturated alpha-Ketoamides for the Construction of Nonracemic gamma,gamma-Diarylcarbonyl Compounds

	Rhodium-Catalyzed Asymmetric Arylation of beta,gamma-Unsaturated alpha-Ketoamides for the Construction of Nonracemic gamma,gamma-Diarylcarbonyl Compounds
	Wang, Juanjuan ; Wang, Min ; Cao, Peng ; Jiang, Liyin ; Chen, Guihua ; Liao, Jian
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2014
卷号	53 期号:26 页码:6673-6677
关键词	asymmetric synthesis enantioselectivity homogeneous catalysis rhodium S P ligands
通讯作者	Liao, J (reprint author), Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China.
产权排序	3
合作状况	其它
英文摘要	A highly regio- and enantioselective rhodium-catalyzed 1,4-addition of arylboronic acids to beta,gamma-unsaturated alpha-ketoamides using a simple new chiral sulfinylphosphine ligand is described. This transformation provides an attractive approach to construct chiral nonracemic gamma,gamma-diarylsubstituted carbonyl compounds, as exemplified in the concise syntheses of sertraline and tetrahydroquinoline-2-carboxylamide.
学科主题	Chemistry, Multidisciplinary
收录类别	SCI
语种	英语
公开日期	2016-02-26
内容类型	期刊论文
源URL	[http://210.75.237.14/handle/351003/26680]
专题	成都生物研究所_天然产物研究
推荐引用方式 GB/T 7714	Wang, Juanjuan,Wang, Min,Cao, Peng,et al. Rhodium-Catalyzed Asymmetric Arylation of beta,gamma-Unsaturated alpha-Ketoamides for the Construction of Nonracemic gamma,gamma-Diarylcarbonyl Compounds[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2014,53(26):6673-6677.
APA	Wang, Juanjuan,Wang, Min,Cao, Peng,Jiang, Liyin,Chen, Guihua,&Liao, Jian.(2014).Rhodium-Catalyzed Asymmetric Arylation of beta,gamma-Unsaturated alpha-Ketoamides for the Construction of Nonracemic gamma,gamma-Diarylcarbonyl Compounds.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,53(26),6673-6677.
MLA	Wang, Juanjuan,et al."Rhodium-Catalyzed Asymmetric Arylation of beta,gamma-Unsaturated alpha-Ketoamides for the Construction of Nonracemic gamma,gamma-Diarylcarbonyl Compounds".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 53.26(2014):6673-6677.