Hydrodeoxygenation of angelica lactone dimers and trimers over silica-alumina supported nickel catalyst

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	Hydrodeoxygenation of angelica lactone dimers and trimers over silica-alumina supported nickel catalyst
	Ayodele, Olubunmi O.1,2,3; Dawodu, Folasegun A.2; Yan, Dongxia 1; Lu, Xingmei 1; Xin, Jiayu 1; Zhang, Suojiang 1
刊名	RENEWABLE ENERGY
	2016-02-01
卷号	86 期号:FEB 页码:943-948
关键词	Angelica lactone Levulinic acid Di/trimerization Biogasoline Bifunctional catalyst
ISSN号	0960-1481
英文摘要	Fractionation of biomass to furan derivatives followed by hydrodeoxygenation could provide an efficient route for bioalkanes production. A simple catalytic process to obtain fuels rich in alkanes with 8-12 carbons via hydrodeoxygenation of biomass-derived angelica lactone dimers/trimers was investigated. Dimers and trimers obtained by C-C coupling of alpha- and beta-angelica lactones were hydrodeoxygenated over a bifunctional catalyst, nickel supported on silica-alumina (Ni/SiO2-Al2O3). Reaction conditions such as hydrogen pressure, temperature and time were considered and it was observed that changes in reaction conditions had significant effect on product distributions. Effective conversion of di/trimers of angelica lactone was achieved over Ni/SiO2-Al2O3 with highly branched alkanes and aromatics being selectively produced. The hydrogenated products which are similar in composition to fossil-derived gasoline could further encourage research into more efficient processes to produce bioalkanes on an industrial scale. (C) 2015 Elsevier Ltd. All rights reserved.
WOS标题词	Science & Technology ; Technology
类目[WOS]	Energy & Fuels
研究领域[WOS]	Energy & Fuels
关键词[WOS]	TRANSPORTATION FUELS ; GAMMA-VALEROLACTONE ; BIOMASS ; LIQUID ; CONVERSION ; ALKANES ; HYDROCARBONS ; CHEMICALS
收录类别	SCI
语种	英语
WOS记录号	WOS:000364248300093
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/19772]
专题	过程工程研究所_多相复杂系统国家重点实验室
作者单位	1.Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Key Lab Green Proc & Engn, Inst Proc Engn, Beijing 100190, Peoples R China 2.Univ Ibadan, Dept Chem Ind, Ibadan, Oyo State, Nigeria 3.Forestry Res Inst Nigeria, Dept Forest Prod Dev & Utilizat, Ibadan, Oyo State, Nigeria
推荐引用方式 GB/T 7714	Ayodele, Olubunmi O.,Dawodu, Folasegun A.,Yan, Dongxia,et al. Hydrodeoxygenation of angelica lactone dimers and trimers over silica-alumina supported nickel catalyst[J]. RENEWABLE ENERGY,2016,86(FEB):943-948.
APA	Ayodele, Olubunmi O.,Dawodu, Folasegun A.,Yan, Dongxia,Lu, Xingmei,Xin, Jiayu,&Zhang, Suojiang.(2016).Hydrodeoxygenation of angelica lactone dimers and trimers over silica-alumina supported nickel catalyst.RENEWABLE ENERGY,86(FEB),943-948.
MLA	Ayodele, Olubunmi O.,et al."Hydrodeoxygenation of angelica lactone dimers and trimers over silica-alumina supported nickel catalyst".RENEWABLE ENERGY 86.FEB(2016):943-948.