N-Heterocyclic Carbene-Catalyzed Formal [3+2] Annulation of Alkynyl Aldehydes with Nitrosobenzenes: A Highly Regioselective Umpolung Strategy

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	N-Heterocyclic Carbene-Catalyzed Formal [3+2] Annulation of Alkynyl Aldehydes with Nitrosobenzenes: A Highly Regioselective Umpolung Strategy
	Han, Runfeng 1; Qi, Jing 1; Gu, Jixiang 1; Ma, Donghui 1; Xie XG(谢新刚)1; She XG(厍学功)1,2
刊名	ACS Catalysis
	2013
卷号	3 期号:12 页码:2705-2709
关键词	N-heterocyclic carbene [3+2] annulation regioselective umpolung alkynyl aldehydes nitrosobenzenes
ISSN号	2155-5435
通讯作者	厍学功
英文摘要	N-Heterocyclic carbene-catalyzed formal [3+2] annulation of alkynyl aldehydes and nitrosobenzenes has been reported. This transformation provided the novel C-X bond formation under mild conditions in moderate to satisfactory yields. The catalytic protocol allows for a rapid construction of 2,5-disubstituted isoxazol-3(2H)-ones and 2,3-disubstituted isoxazol-5(2H)-ones from the same materials via a highly regioselectively umpolung stratgy.
学科主题	物理化学与绿色催化
收录类别	SCI
资助信息	the NSFC (21125207;21102062;21072086);the MOST (2010CB833202);PCSIRT (IRT1138);the FRFCU (lzujbky-2013-49;lzujbky-2013-ct02);Program 111
语种	英语
WOS记录号	WOS:000328231400007
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/18208]
专题	兰州化学物理研究所_OSSO国家重点实验室
作者单位	1.Lanzhou Univ, State Key Lab Appl Organ Chem, Coll Chem & Chem Engn, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China
推荐引用方式 GB/T 7714	Han, Runfeng,Qi, Jing,Gu, Jixiang,et al. N-Heterocyclic Carbene-Catalyzed Formal [3+2] Annulation of Alkynyl Aldehydes with Nitrosobenzenes: A Highly Regioselective Umpolung Strategy[J]. ACS Catalysis,2013,3(12):2705-2709.
APA	Han, Runfeng,Qi, Jing,Gu, Jixiang,Ma, Donghui,Xie XG,&She XG.(2013).N-Heterocyclic Carbene-Catalyzed Formal [3+2] Annulation of Alkynyl Aldehydes with Nitrosobenzenes: A Highly Regioselective Umpolung Strategy.ACS Catalysis,3(12),2705-2709.
MLA	Han, Runfeng,et al."N-Heterocyclic Carbene-Catalyzed Formal [3+2] Annulation of Alkynyl Aldehydes with Nitrosobenzenes: A Highly Regioselective Umpolung Strategy".ACS Catalysis 3.12(2013):2705-2709.