Disposable ionic liquid coating for headspace solid-phase microextraction of benzene, toluene, ethylbenzene. and xylenes in paints followed by gas chromatography-flame ionization detection

CORC > 生态环境研究中心 > 中国科学院生态环境研究中心 > 环境化学与生态毒理学国家重点实验室

	Disposable ionic liquid coating for headspace solid-phase microextraction of benzene, toluene, ethylbenzene. and xylenes in paints followed by gas chromatography-flame ionization detection
	Liu, JF; Li, N; Jiang, GB; Li, JM; Jonsson, JA; Wen, MJ
刊名	JOURNAL OF CHROMATOGRAPHY A
	2005
卷号	1066 期号:2015-01-02 页码:27-32
关键词	ionic liquid solid-phase microextraction disposable coating benzene toluene ethylbenzene xylenes paint analysis
英文摘要	Solid-phase microextraction (SPME) with a disposable ionic liquid (IL) coating was developed for headspace extraction of benzene, toluene, ethylbenzene, and xylenes (BTEX) in paints. The SPME fiber was coated with IL prior to every extraction, then the analytes were extracted and desorbed on the injection port of gas chromatography, and finally the IL coating on the fiber was washed out with solvents. The coating and washing out of IL from the fiber can be finished in a few minutes. This disposable IL-coated fiber was applied to determine BTEX in water-soluble paints with results in good agreement with that obtained by using commercially available SPME fibers. For all the four studied paints samples, the benzene contents were under the detection limits, but relatively high contents of toluene, ethylbenzene and xylenes (56-271 mug g(-1)) were detected with spiked recoveries in the range of 70-114%. Compared to the widely used commercially available SPME fibers, this proposed disposable IL-coated fiber has much lower cost per determination, comparable reproducibility (RSD < 11%), and no carryover between each determination. Considering that IL possess good extractability for various organic compounds and metals ions, and that task-specific IL can be designed and synthesized for selective extraction of target analytes, this disposable IL coating SPME might has great potential in sample preparation. (C) 2005 Elsevier B.V. All rights reserved.
学科主题	Biochemistry & Molecular Biology ; Chemistry
研究领域[WOS]	Biochemistry & Molecular Biology ; Chemistry
WOS记录号	WOS:000227503600004
内容类型	期刊论文
源URL	[http://ir.rcees.ac.cn/handle/311016/23171]
专题	生态环境研究中心_环境化学与生态毒理学国家重点实验室
推荐引用方式 GB/T 7714	Liu, JF,Li, N,Jiang, GB,et al. Disposable ionic liquid coating for headspace solid-phase microextraction of benzene, toluene, ethylbenzene. and xylenes in paints followed by gas chromatography-flame ionization detection[J]. JOURNAL OF CHROMATOGRAPHY A,2005,1066(2015-01-02):27-32.
APA	Liu, JF,Li, N,Jiang, GB,Li, JM,Jonsson, JA,&Wen, MJ.(2005).Disposable ionic liquid coating for headspace solid-phase microextraction of benzene, toluene, ethylbenzene. and xylenes in paints followed by gas chromatography-flame ionization detection.JOURNAL OF CHROMATOGRAPHY A,1066(2015-01-02),27-32.
MLA	Liu, JF,et al."Disposable ionic liquid coating for headspace solid-phase microextraction of benzene, toluene, ethylbenzene. and xylenes in paints followed by gas chromatography-flame ionization detection".JOURNAL OF CHROMATOGRAPHY A 1066.2015-01-02(2005):27-32.