Phosphine-containing microporous networks: High selectivity toward carbon dioxide to methane

CORC > 青岛生物能源与过程研究所 > 中国科学院青岛生物能源与过程研究所 > 先进有机功能材料团队

	Phosphine-containing microporous networks: High selectivity toward carbon dioxide to methane
	Qiao, Shanlin 1,2; Du, Zhengkun 1; Yang, Chunpeng 1; Zhou, Yuanhang 1; Zhu, Dangqiang 1; Wang, Jiuxing 1; Chen, Xianghui 1; Yang, Renqiang1
刊名	POLYMER
	2014-03-10
卷号	55 期号:5 页码:1177-1182
关键词	Phosphine-containing microporous organic polymer Carbon dioxide adsorption Methane adsorption
英文摘要	Two phosphine-containing microporous organic networks TPPDEB-O and TPPDEB-S were designed and synthesized via Sonogashira Hagihara coupling condensation reaction. The electronic structures and the adsorption characteristics of the polymers can be tailored by facile oxidation and vulcanization modification of the nucleophilic phosphorus atom node. Nitrogen adsorption desorption isotherms of TPPDEB-O and TPPDEB-S showed the Brunauer Emmet Teller specific surface areas were 712.51 m(2) g(-1) and 677.02 m(2) g(-1), respectively. The two frameworks have strong affinity for CO2 and the isosteric heats of sorption were excess 25 Ki morl at the whole loading range. Furthermore, their selectivity toward CO2/CH4 exceeded most of porous organic polymers and the surfaces functionalized by P=O or showed a large different capacity on the CO2/CH4 separation (TPPDEB-O and TPPDEB-S at 273 K is 15.9, 5.5 and at 298 K is 9.3, 4.3, respectively). (C) 2014 Elsevier Ltd. All rights reserved.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Polymer Science
研究领域[WOS]	Polymer Science
关键词[WOS]	COVALENT ORGANIC FRAMEWORKS ; PI-CONJUGATED MATERIALS ; HIGH-SURFACE-AREA ; INTRINSIC MICROPOROSITY ; ENERGY APPLICATIONS ; HYDROGEN STORAGE ; ISOSTERIC HEAT ; POLYMERS ; ADSORPTION ; GAS
收录类别	SCI
语种	英语
WOS记录号	WOS:000332500600013
公开日期	2015-12-24
内容类型	期刊论文
源URL	[http://ir.qibebt.ac.cn/handle/337004/6148]
专题	青岛生物能源与过程研究所_先进有机功能材料团队
作者单位	1.Chinese Acad Sci, CAS Key Lab Biobased Mat, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Qiao, Shanlin,Du, Zhengkun,Yang, Chunpeng,et al. Phosphine-containing microporous networks: High selectivity toward carbon dioxide to methane[J]. POLYMER,2014,55(5):1177-1182.
APA	Qiao, Shanlin.,Du, Zhengkun.,Yang, Chunpeng.,Zhou, Yuanhang.,Zhu, Dangqiang.,...&Yang, Renqiang.(2014).Phosphine-containing microporous networks: High selectivity toward carbon dioxide to methane.POLYMER,55(5),1177-1182.
MLA	Qiao, Shanlin,et al."Phosphine-containing microporous networks: High selectivity toward carbon dioxide to methane".POLYMER 55.5(2014):1177-1182.